Excess molar enthalpies of the ternary mixtures:: (diisopropyl ether or 2-methyltetrahydrofuran) plus cyclohexane plus n-heptane at 298.15 K

被引：5

作者：

Wang, ZH ^{[1
]}

Benson, GC ^{[1
]}

Lu, BCY ^{[1
]}

机构：

[1] Univ Ottawa, Dept Chem Engn, Ottawa, ON K1N 6N5, Canada

来源：

THERMOCHIMICA ACTA | 2003年 / 400卷 / 1-2期

基金：

加拿大自然科学与工程研究理事会;

关键词：

diisopropyl ether; cyclohexane; 2-methyltetrahyrdrofuran; n-heptane; excess molar enthalpy; ternary system; Liebermann-Fried model;

D O I：

10.1016/S0040-6031(02)00479-3

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Microcalorimetric measurements of excess molar enthalpies, at 298.15 K, are reported for the two ternary systems formed by mixing either diisopropyl ether or 2-methyltetrahydrofuran with binary mixtures of cyclohexane and n-heptane. Smooth representations of the results are presented and used to construct constant excess molar enthalpy contours on Roozeboom diagrams. It is shown that useful estimates of the ternary enthalpies can be obtained from the Liebermann and Fried model, using only the physical properties of the components and their binary mixtures. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：69 / 77

页数：9

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