The synthesis of a dicyclopenta[a,e]pentalene via a molybdenum hexacarbonyl-mediated tandem allenic Pauson-Khand reaction

被引：50

作者：

Cao, H

Flippen-Anderson, J

Cook, JM

机构：

[1] Univ Wisconsin, Dept Chem, Milwaukee, WI 53201 USA

[2] USN, Res Lab, Struct Matter Lab, Washington, DC 20375 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 11期

关键词：

D O I：

10.1021/ja021159+

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An approach to the 14π annulene has been developed, by employing the molybdenum hexacarbonyl-mediated tandem allenic Pauson-Khand reaction as a key step. A di-triisopropylsilyl substituted dicyclopenta[a,e]pentalene was synthesized. This 14π annulene showed some electronic delocalization, which was not observed in previous cases. Copyright © 2003 American Chemical Society.

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页码：3230 / 3231

页数：2

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