Molecular spinning top: visualizing the dynamics of M3N@C80 with variable temperature single crystal X-ray diffraction

被引：12

作者：

Liu, Fupin ^{[1
]}

Spree, Lukas ^{[1
]}

机构：

[1] Leibniz Inst Solid State & Mat Res IFW Dresden, Helmholtzstr 20, D-01069 Dresden, Germany

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 86期

关键词：

ENDOHEDRAL METALLOFULLERENES; METAL ATOMS; CARBON; CLUSTER; LOCATION; ROTATION; CAGES; IONS; SIZE; LU;

D O I：

10.1039/c9cc06363c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Variable temperature X-ray diffraction studies on two single crystals containing M3N@C-80, i.e., Ho2LuN@C-80 center dot NiOEP center dot 2(C6H6) and Lu3N@C-80 center dot NiOEP center dot 2(C6H6), (NiOEP = Nickel octaethylporphyrin) unravelled the temperature dependent rotation of the M3N cluster and C-80 cage on the static NiOEP molecule.

引用

页码：13000 / 13003

页数：4

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