Enhancement of Photocatalytic Activity of TiO2 by High-Energy Electron-Beam Treatment Under Atmospheric Pressure

被引:19
作者
Kim, Myoung Joo [1 ]
Kim, Kwang-Dae [1 ]
Tai, Wei Sheng [1 ]
Seo, Hyun Ook [1 ]
Luo, Yuan [1 ]
Kim, Young Dok [1 ]
Lee, Byung Cheol [2 ]
Park, Ok Kyung [2 ]
机构
[1] Sungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea
[2] Korea Atom Energy Res Inst, Quantum Opt Res Div, Taejon 305353, South Korea
关键词
High-energy e-beam; Surface treatment; Photocatalysis; TiO2; OXIDATION; WATER; TOLUENE; PHASE;
D O I
10.1007/s10562-010-0267-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The influence of high-energy e-beam treatment at atmospheric pressure on the structure and photocatalytic activity of TiO2 was examined. Using an e-beam energy of 1 MeV and exposure in the range of 5-15 kGy, an improvement in the photocatalytic activity of TiO2 was observed. An increase in the population of C-O bonds was found in the C and O 1s states using X-ray Photoelectron Spectroscopy (XPS) suggesting that the change in the structure of the C impurities on the surface of TiO2 is closely related to the variation in the photocatalytic activity.
引用
收藏
页码:57 / 61
页数:5
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