Cluster chemistry in the Noughties: new developments and their relationship to nanoparticles

被引：67

作者：

Hogarth, Graeme ^{[1
]}

Kabir, Shariff E. ^{[2
]}

Nordlander, Ebbe ^{[3
]}

机构：

[1] UCL, Dept Chem, London WC1H 0AJ, England

[2] Jahangirnagar Univ, Dept Chem, Dhaka 1342, Bangladesh

[3] Lund Univ, Ctr Chem & Chem Engn, Inorgan Chem Res Grp, SE-22100 Lund, Sweden

来源：

DALTON TRANSACTIONS | 2010年 / 39卷 / 27期

关键词：

N-HETEROCYCLIC CARBENE; TRANSITION-METAL CLUSTERS; PROTECTED GOLD CLUSTERS; LARGE-SCALE SYNTHESIS; X-RAY STRUCTURES; CARBONYL CLUSTERS; STRUCTURAL-CHARACTERIZATION; TRIRUTHENIUM CLUSTER; TRIOSMIUM CLUSTER; RUTHENIUM CLUSTER;

D O I：

10.1039/c000514b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Over the past decade, the chemistry of low-valent transition metal clusters has again come to the fore, primarily as a result of the development of nanochemistry and the realization that large clusters are on the cusp of the nano-domain. This perspective focuses on these recent developments in low-valent transition metal cluster chemistry, specifically looking at cluster-nanoparticles, the use of small and medium sized clusters as nanoparticle precursors, the development of clusters as homogeneous catalysts and hydrogen uptake and storage systems, together with fundamental discoveries relating to novel transformations that can take place within the cluster framework.

引用

收藏

页码：6153 / 6174

页数：22

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