Complexation of C60 with hexahomooxacalix[3]arenes and supramolecular structures of complexes in the solid state

被引：98

作者：

Tsubaki, K

Tanaka, K

Kinoshita, T

Fuji, K ^{[1
]}

机构：

[1] Kyoto Univ, Inst Chem Res, Uji, Kyoto 6110011, Japan

[2] Fujisawa Pharmaceut Co Ltd, Basic Res Labs, Yodogawa Ku, Osaka 5328514, Japan

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 08期

关键词：

D O I：

10.1039/a800078f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hexahomooxacalix[3]arenes 1-5, which possess a variety of substituents on their upper rim, have captured fullerene C-60 in toluene with association constants of K-a = 9.1-35.6 dm(3) mol(-1); X-ray analysis of the complex of C-60 and 4 indicated that a van der Waals attractive interaction is the dominant driving force which brings the hexagonal faces of the C-60 close to both the aromatic rings and the dibenzyl ether oxygen of 4.

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页码：895 / 896

页数：2

相关论文

共 20 条

[1] A GAS-PHASE CONTAINER FOR C-60 - A GAMMA-CYCLODEXTRIN DIMER [J].

ANDERSSON, T ;

WESTMAN, G ;

STENHAGEN, G ;

SUNDAHL, M ;

WENNERSTROM, O .

TETRAHEDRON LETTERS, 1995, 36 (04) :597-600

[2] Molecular design of calixarene-based host molecules for inclusion of C-60 in solution [J].

Araki, K ;

Akao, K ;

Ikeda, A ;

Suzuki, T ;

Shinkai, S .

TETRAHEDRON LETTERS, 1996, 37 (01) :73-76

[3] PURIFICATION OF C-60 AND C-70 BY SELECTIVE COMPLEXATION WITH CALIXARENES [J].

ATWOOD, JL ;

KOUTSANTONIS, GA ;

RASTON, CL .

NATURE, 1994, 368 (6468) :229-231

[4]

ATWOOD JL, 1996, J CHEM SOC CHEM COMM, P1449

[5] PREPARATION AND CHARACTERIZATION OF C-60(FERROCENE)2 [J].

CRANE, JD ;

HITCHCOCK, PB ;

KROTO, HW ;

TAYLOR, R ;

WALTON, DRM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (24) :1764-1765

[6] CRYSTALLOGRAPHIC CHARACTERIZATION OF THE LATTICE STRUCTURE C60[FE4(CO)4(ETA-5-C5H5)4] AS THE 1/3 BENZENE SOLVATE [J].

CRANE, JD ;

HITCHCOCK, PB .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (16) :2537-2538

[7] CALIXARENES .10. OXACALIXARENES [J].

DHAWAN, B ;

GUTSCHE, CD .

JOURNAL OF ORGANIC CHEMISTRY, 1983, 48 (09) :1536-1539

[8]

DIEDERICH F, 1992, ANGEW CHEM INT EDIT, V31, P1599

[9] [60]FULLERENE AND TCNQ DONOR-ACCEPTOR CRYSTALS OF OCTAKIS(DIMETHYLAMINO)PORPHYRAZINE [J].

EICHHORN, DM ;

YANG, SL ;

JARRELL, W ;

BAUMANN, TF ;

BEALL, LS ;

WHITE, AJP ;

WILLIAMS, DJ ;

BARRETT, AGM ;

HOFFMAN, BM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (16) :1703-1704

[10] New supramolecular complex of C-60 based on calix[5]arene - Its structure in the crystal and in solution [J].

Haino, T ;

Yanase, M ;

Fukazawa, Y .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (03) :259-260