Flexible and Hierarchical Metal-Organic Framework Composites for High-Performance Catalysis

被引：107

作者：

Huang, Ning ^{[1
]}

Drake, Hannah ^{[1
]}

Li, Jialuo ^{[1
]}

Pang, Jiandong ^{[1
]}

Wang, Ying ^{[1
,2
]}

Yuan, Shuai ^{[1
]}

Wang, Qi ^{[1
]}

Cai, Peiyu ^{[1
]}

Qin, Junsheng ^{[1
]}

Zhou, Hong-Cai ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

[2] Tianjin Normal Univ, Coll Chem, Tianjin 300387, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2018年 / 57卷 / 29期

关键词：

composite materials; heterogeneous catalysis; metal-organic frameworks; porous materials; EPOXIDATION; PORPHYRINS; GROWTH; FOAM;

D O I：

10.1002/anie.201803096

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The development of porous composite materials is of great significance for their potentially improved performance over those of individual components and extensive applications in separation, energy storage, and heterogeneous catalysis. Now mesoporous metal-organic frameworks (MOFs) with macroporous melamine foam (MF) have been integrated using a one-pot process, generating a series of MOF/MF composite materials with preserved crystallinity, hierarchical porosity, and increased stability over that of melamine foam. The MOF nanocrystals were threaded by the melamine foam networks, resembling a ball-and-stick model overall. The resulting MOF/MF composite materials were employed as an effective heterogeneous catalyst for the epoxidation of cholesteryl esters. Combining the advantages of interpenetrative mesoporous and macroporous structures, the MOF/melamine foam composite has higher dispersibility and more accessibility of catalytic sites, exhibiting excellent catalytic performance.

引用

页码：8916 / 8920

页数：5

共 34 条

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