Rational design of phosphonocarboxylate metal-organic frameworks for light hydrocarbon separations

被引：19
|
作者：
Li, Lan [1 ]
Yin, Qi [1 ]
Li, Hong-Fang [1 ]
Liu, Tian-Fu [1 ]
Cao, Rong [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
来源：
MATERIALS CHEMISTRY FRONTIERS | 2018年 / 2卷 / 08期
基金：
中国国家自然科学基金;
关键词：
HIGHLY SELECTIVE SEPARATION; ROOM-TEMPERATURE; ADSORPTION; CO2; STORAGE; GAS; MOF; METHANE; ETHANE; WATER;
D O I：
10.1039/c8qm00029h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Metal-organic frameworks (MOFs) provoke intensive research interests on separations of small gas molecules. By introducing a coordinative phosphate group into a carboxylic acid linker, a ligand 4,4-(hydroxyphosphoryl) dibenzoic acid (H(3)hpda) was successfully synthesized and used to construct microporous phosphonocarboxylate framework [Cu-3(hpda)(2)DMF2H(2)O]3DMFH(2)O (DMF = N,N-dimethylformamide) and [Mg-3((2)-OH2)(2)(OH2)(2)(hpda)(2)]3DMF2H(2)O. Both of them possess narrow approachable channels and exhibit excellent performance on selective separation of light hydrocarbons (C-1-C-2), presenting a promising ligand design strategy for the construction of porous material aiming for natural gas upgrading.
引用
收藏
页码：1436 / 1440
页数：6
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