2-Ferrocenyl-N-(6-methyl-2-pyridyl)benzamide

被引：0

作者：

Gallagher, John F. ^{[1
]}

Alley, Steven ^{[1
]}

Lough, Alan J. ^{[2
]}

机构：

[1] Dublin City Univ, Sch Chem Sci, Dublin 9, Ireland

[2] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

D O I：

10.1107/S1600536810008342

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Fe(C(5)H(5))(C(18)H(15)N(2)O)], a product of the reaction of 2-ferrocenylbenzoic acid and 2-amino-6-methylpyridine, crystallizes with two dissimilar molecules in the asymmetric unit. In one molecule, the picoline amide group is directed away from the 2-ferrocenylbenzene moiety (anti) whereas in the other, these are proximate (syn). In the crystal structure, molecules aggregate into dimers via cyclic, asymmetric N-H center dot center dot center dot N interactions with graph set R(2)(2)(8), and are further augmented via intramolecular C-H center dot center dot center dot O=C and interdimer C-H center dot center dot center dot pi(arene) interactions. Dimers are linked into chains along the [102] direction via weak C-H center dot center dot center dot O hydrogen bonds.

引用

页码：M396 / U569

页数：22

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