Fabrication of polymeric thin films by a self-assembly method

被引：2

作者：

Nishiwaki, Y ^{[1
]}

Takeoka, Y ^{[1
]}

Rikukawa, M ^{[1
]}

Sanui, K ^{[1
]}

机构：

[1] Sophia Univ, Dept Chem, Chiyoda Ku, Tokyo 1028554, Japan

来源：

SYNTHETIC METALS | 2003年 / 137卷 / 1-3期

关键词：

self-assembly; condensing agents; amide bonding;

D O I：

10.1016/S0379-6779(02)01188-8

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Polymeric thin films which had a high-ordered structure were fabricated from adipic acid (ADA), 4,4'-diaminodiphenylmethane dihydrochloride (DAM), and N-hydroxysuccinimide (NHS) and 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide hydrochloride (EDC) as condensing agents by a self-assembly method. UV-Vis and quartz crystal microbalance (QCM) measurements were used to monitor the layer-by-layer deposition process. FTIR reflection absorption spectroscopy (FTIR-RAS) was also carried out in order to confirm the polymerization of monomers. The surface morphology of the films was investigated with an atomic force microscope (AFM). These results indicated that ADA and DAM were alternately deposited and polymerized with condensing agents on nanoscale.

引用

页码：931 / 932

页数：2

共 6 条

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