Cyclopalladated ferrocenylimine: a highly effective catalyst for the borylation/suzuki coupling reaction

被引：31

作者：

Ma, Ning ^{[1
]}

Zhu, Zhiwu ^{[1
]}

Wu, Yangjie ^{[1
]}

机构：

[1] Zhengzhou Univ, Dept Chem, Henan Key Lab Chem Biol & Organ Chem, Key Lab Appl Chem Henan Univ, Zhengzhou 450052, Peoples R China

来源：

TETRAHEDRON | 2007年 / 63卷 / 22期

基金：

中国国家自然科学基金;

关键词：

cyclopalladated ferrocenylimine; bis(pinacolato)diboron; one-pot borylation; Suzuki cross-coupling;

D O I：

10.1016/j.tet.2007.03.108

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The cyclopalladated ferrocenylimine was an efficient catalyst for the borylation/Suzuki coupling reaction. The catalytic loading for the reaction containing bromoarenes was 1 mol %. When iodobenzene was used, the catalytic loading was as low as 0.1 mol %. Furthermore, the cyclopalladated ferrocenylimine also exhibited excellent catalytic power in the case of substrates containing electron-donating substituents, with yields reaching 93% or higher. (C) 2007 Elsevier Ltd. All rights reserved.

引用

页码：4625 / 4629

页数：5

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