Carbon Dioxide Capture by Superbase-Derived Protic Ionic Liquids

被引：476

作者：

Wang, Congmin ^{[1
,2
]}

Luo, Huimin ^{[3
]}

Jiang, De-en ^{[2
]}

Li, Haoran ^{[1
]}

Dai, Sheng ^{[2
]}

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China

[2] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA

[3] Oak Ridge Natl Lab, Nucl Sci & Technol Div, Oak Ridge, TN 37831 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 34期

基金：

中国国家自然科学基金;

关键词：

anions; carbon capture; carbon dioxide; ionic liquids; superbases; ROOM-TEMPERATURE; SOLVATOCHROMIC DYE; CO2; SOLUBILITY; ABSORPTION; CHEMISTRY; BASICITY;

D O I：

10.1002/anie.201002641

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

CO2 capture: Protic ionic liquids (PILs) from a Superbase and fluorinated alcohol, imidazole, pyrrolinone, or phenol were designed to capture CO2 based on the reactivity of their anions to CO2. These PILs are capable of rapid and reversible capture of about one equivalent of CO2, which is superior to those sorption systems based on traditional aprotic ILs. (Figure Presented).

引用

页码：5978 / 5981

页数：4

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