Photochemical Control of Reversible Encapsulation

被引：74

作者：

Dube, Henry ^{[1
,2
]}

Ajami, Dariush ^{[1
,2
]}

Rebek, Julius, Jr. ^{[1
,2
]}

机构：

[1] Scripps Res Inst, Skaggs Inst Chem Biol, La Jolla, CA 92037 USA

[2] Scripps Res Inst, Dept Chem, La Jolla, CA 92037 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 18期

基金：

瑞士国家科学基金会;

关键词：

azobenzenes; encapsulation; host-guest chemistry; photoisomerization; supramolecular chemistry; PHOTORESPONSIVE CROWN-ETHERS; RESONANCE ENERGY-TRANSFER; CYLINDRICAL CAPSULE; MOLECULAR CAPSULE; MULTICOMPONENT; COMPLEXATION; AZOBENZENE; HOST;

D O I：

10.1002/anie.201000876

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Remote control: Molecules can be transferred in a chemical system between capsules and bulk solution by using light and heat. The principle is based on the isomerization of azobenzene, the trans isomer of which is encapsulated, but the cis isomer is not (see picture; C gray and brown, Br mauve; O red, N blue, H white). The photochemical control can also be used to switch between different capsular assemblies. © 2010 Wiley-VCH Verlag GmbH S. Co. KGaA.

引用

页码：3192 / 3195

页数：4

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