Controlling the bonding of CO on cobalt clusters by coadsorption of H2

被引：19
|
作者：
Swart, Ingmar
Fielicke, Andre
Rayner, David M.
Meijer, Gerard
Weckhuysen, Bert M.
de Groot, Frank M. F.
机构：
[1] Max Planck Gesell, Fritz Haber Inst, D-14195 Berlin, Germany
[2] Univ Utrecht, Fac Sci, Dept Chem, NL-3584 CA Utrecht, Netherlands
[3] Natl Res Council Canada, Steacie Inst Mol Sci, Ottawa, ON K1A 0R6, Canada
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 28期
关键词：
carbon monoxide; cluster compounds; coadsorption; cobalt; IR spectroscopy;
D O I：
10.1002/anie.200605165
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
H in control (of the electrons): The bond strength of CO on small cationic cobalt clusters, as indicated by the C-O stretching band in the IR spectrum, can be precisely controlled by coadsorption of H2 molecules. Each coadsorbed H atom reduces the electron density available for back-donation by about 0.09-0.25 electrons, depending on cluster size. (Graph Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：5317 / 5320
页数：4
相关论文
共 50 条
  • [41] Microcalorimetric studies of H2 and CO on Co/γ-Al2O3 catalysts for Fischer-Tropsch synthesis
    Patanou, Eleni
    Tveten, Erik Z.
    Chen, De
    Holmen, Anders
    Blekkan, Edd A.
    CATALYSIS TODAY, 2013, 214 : 19 - 24
  • [42] Catalytic H2 Evolution by a Mononuclear Cobalt Complex with a Macrocyclic Pentadentate Ligand
    Wang, Ping
    Liang, Guangchao
    Boyd, Chanteal Laquita
    Webster, Charles Edwin
    Zhao, Xuan
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2019, 2019 (15) : 2134 - 2139
  • [43] Density functional theory study on the adsorption of H, OH, and CO and coadsorption of CO with H/OH on the Pt2Ru3 surfaces
    Alam, Md. Khorshed
    Saito, Shuhei
    Takaba, Hiromitsu
    JOURNAL OF MATERIALS RESEARCH, 2016, 31 (17) : 2617 - 2626
  • [44] CO•••H2O bonding in and on porous ices
    Givan, A
    Loewenschuss, A
    Nielsen, CJ
    VIBRATIONAL SPECTROSCOPY, 1998, 16 (01) : 85 - 88
  • [45] Experimental Microkinetic Approach of the Surface Reconstruction of Cobalt Particles in Relationship with the CO/H2 Reaction on a Reduced 10% Co/Al2O3 Catalyst
    Couble, Julien
    Bianchi, Daniel
    JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (28) : 14544 - 14557
  • [46] PEMFC contaminant tolerance limit-CO in H2
    St-Pierre, Jean
    ELECTROCHIMICA ACTA, 2010, 55 (13) : 4208 - 4211
  • [47] CO AND H2 ABSORPTION IN THE AA TAURI CIRCUMSTELLAR DISK
    France, Kevin
    Burgh, Eric B.
    Herczeg, Gregory J.
    Schindhelm, Eric
    Yang, Hao
    Abgrall, Herve
    Roueff, Evelyne
    Brown, Alexander
    Brown, Joanna M.
    Linsky, Jeffrey L.
    ASTROPHYSICAL JOURNAL, 2012, 744 (01)
  • [48] Coadsorption of CO and O2 on Pd(111)
    Kuittinen, RL
    Laasonen, K
    CHEMICAL PHYSICS, 2005, 314 (1-3) : 19 - 24
  • [49] Populating H2 and CO in galaxy simulation with dust evolution
    Chen, Li-Hsin
    Hirashita, Hiroyuki
    Hou, Kuan-Chou
    Aoyama, Shohei
    Shimizu, Ikkoh
    Nagamine, Kentaro
    MONTHLY NOTICES OF THE ROYAL ASTRONOMICAL SOCIETY, 2018, 474 (02) : 1545 - 1563
  • [50] Photocatalytic Oxidation of CO on TiO2: Chemisorption of O2, CO, and H2
    Dai, Wenxin
    Chen, Xun
    Zheng, Xiangping
    Ding, Zhengxin
    Wang, Xuxu
    Liu, Ping
    Fu, Xianzhi
    CHEMPHYSCHEM, 2009, 10 (02) : 411 - 419
12345