Photoswitching of triplet-triplet annihilation upconversion showing large emission shifts using a photochromic fluorescent dithienylethene-Bodipy triad as a triplet acceptor/emitter

被引:36
作者
Xu, Kejing [1 ]
Zhao, Jianzhang [1 ]
Cui, Xiaoneng [1 ]
Ma, Jie [1 ]
机构
[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China
关键词
TRANSITION-METAL-COMPLEXES; LOW-POWER; DIARYLETHENE; NANOPARTICLES; MODULATION; LIGHT; PHOTOCYCLIZATION; MEMORIES; SWITCHES; LIGANDS;
D O I
10.1039/c4cc09202c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A photoswitchable fluorescent triad based on dithienylethene and Bodipy was used as a triplet acceptor/emitter for reversible photo-switching of triplet-triplet-annihilation upconversion (with Pd(II) tetraphenyltetrabenzoporphyrin as a triplet photosensitizer), which shows green/near IR emission changes with an emission energy difference of 0.79 eV (Delta lambda = 268 nm).
引用
收藏
页码:1803 / 1806
页数:4
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