Plant sizing and evaluation of hydrogen production costs from advanced processes coupled to a nuclear heat source. Part I: Sulphur-iodine cycle

被引:42
作者
Leybros, J. [2 ]
Gilardi, T. [3 ]
Saturnin, A. [2 ]
Mansilla, C. [1 ]
Carles, P. [4 ]
机构
[1] CEA, DEN, I Tese, F-91191 Gif Sur Yvette, France
[2] CEA, DEN, DTEC, F-30207 Bagnols Sur Ceze, France
[3] CEA, DEN, DTN, F-13108 St Paul Les Durance, France
[4] CEA, DEN, DPC, F-91191 Gif Sur Yvette, France
关键词
Sulphur-iodine cycle; Hydrogen production; Sizing; Costs; WATER-SPLITTING PROCESS; CATALYTIC DECOMPOSITION; THERMOCHEMICAL CYCLE; KINETICS; SOLAR;
D O I
10.1016/j.ijhydene.2009.11.054
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Hydrogen demand is already strong. it should significantly increase in the next few years due to the refinery industry's growing needs and new applications such as synthetic fuel or biofuel production. To meet the demand, advanced processes are being developed throughout the world in a sustainability, context. Among the most studied ones are thermochemical cycles: the sulphur-iodine and hybrid-sulphur cycles. For each of these processes, a thorough study was carried out from the flowsheet development to the final hydrogen production cost assessment, through the sizing and costing of the equipment, providing some insights about the process economic competitiveness given the current state of knowledge. This paper presents the analysis conducted for the sulphur-iodine cycle, which leads to a hydrogen production cost around 12 (sic)/kg. The main contributions to that cost are discussed. (C) 2009 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:1008 / 1018
页数:11
相关论文
共 21 条
[1]  
[Anonymous], [No title captured]
[2]  
*DOE H2A, PROD AN
[3]   Experimental study of the vapour-liquid equilibria of HI-I2-H2O ternary mixtures, Part 1: Experimental results around the atmospheric pressure [J].
Doizi, D. ;
Dauvois, V. ;
Roujou, J. L. ;
Lorin, V. ;
Fauvet, P. ;
Larousse, B. ;
Carles, P. ;
Hartmann, J. M. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (10) :4275-4282
[4]   Hydrogen/methanol production by sulfur-iodine thermochemical cycle powered by combined solar/fossil energy [J].
Giaconia, A. ;
Grena, R. ;
Lanchi, M. ;
Liberatore, R. ;
Tarquini, P. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2007, 32 (04) :469-481
[5]  
GILARDI T, 2006, 16 WORLD HYDR EN C W
[6]  
Godfrey J.C., 1994, LIQUID LIQUID EXTRAC
[7]   Economic comparison of solar hydrogen generation by means of thermochemical cycles and electrolysis [J].
Graf, D. ;
Monnerie, N. ;
Roeb, M. ;
Schmitz, M. ;
Sattler, C. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2008, 33 (17) :4511-4519
[8]  
Karasawa H., 2006, International Journal of Nuclear Hydrogen Production and Applications, V1, P134, DOI 10.1504/IJNHPA.2006.011247
[9]   HYTHEC: An EC funded search for a long term massive hydrogen production route using solar and nuclear technologies [J].
Le Duigou, Alain ;
Borgard, Jean-Marc ;
Larousse, Bruno ;
Doizi, Denis ;
Allen, Ray ;
Ewan, Bruce C. ;
Priestman, Geoff H. ;
Elder, Rachael ;
Devonshire, Robin ;
Ramos, Victor ;
Cerri, Giovanni ;
Salvini, Coriolano ;
Giovannelli, Ambra ;
De Maria, Giovanni ;
Corgnale, Claudio ;
Brutti, Sergio ;
Roeb, Martin ;
Noglik, Adam ;
Rietbrock, Peter-Michael ;
Mohr, Stefan ;
De Oliveira, Lamark ;
Monnerie, Nathalie ;
Schmitz, Mark ;
Sattler, Christian ;
Orden Martinez, Alfredo ;
de Lorenzo Manzano, Daniel ;
Cedillo Rojas, Jorge ;
Dechelotte, Stephane ;
Baudouin, Olivier .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2007, 32 (10-11) :1516-1529
[10]   Countercurrent reactor design and flowsheet for iodine-sulfur thermochemical water splitting process [J].
Leybros, Jean ;
Carles, Philippe ;
Borgard, Jean-Marc .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (22) :9060-9075