Synthesis, Crystal Structure and Spectroscopy Studies on Complex cis-OsII(bpy)2Cl2 and Its Oxidation Product [cis-OsIII(bpy)2Cl2](PF6)

被引：4

作者：

Yu Meng ^{[1
,2
]}

Wang Yong ^{[1
]}

Hu Jian-Mei ^{[1
]}

机构：

[1] Jingchu Univ Technol, Coll Chem Engn & Pharm, Jingmen 444800, Hubei, Peoples R China

[2] Wuhan Inst Technol, Sch Chem Engn & Pharm, Wuhan 430205, Hubei, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2018年 / 37卷 / 06期

关键词：

osmium; crystal structure; electrochemistry; electronic absorption spectra; POLYPYRIDYL COMPLEXES; OSMIUM(II) COMPLEXES; MAGNETIC-PROPERTIES; III M; RUTHENIUM(II); LIGANDS; LUMINESCENT; BINDING; PROBES; REDOX;

D O I：

10.14102/j.cnki.0254-5861.2011-1930

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The treatment of (NH4)(2)OsCl2 with 2 equiv of bpy in ethylene glycol produced complex 1, cis-Os-II(bpy)(2)Cl-2(bpy = 2,2'-bipyridine). Its one-electron oxidation product 2, [cis-Os-III(bpy)(2)Cl-2](PF6), was obtained by the oxidation of 1 with (Cp)(2)FePF6. Complex 1 crystallizes in the orthorhombic space group Pbca, and adopts distorted [MCl2N4] octahedral coordination, in which four coordination sites are occupied by four nitrogen atoms from two bpy ligands and the other two sites are occupied by two chlorine atoms in a cis-position. Complex 2 crystallizes in monoclinic space group C2/c, and contains one [Os(bpy)(2)Cl-2](+) cation, one PF6- anion and two uncoordinated water solvent molecules.

引用

页码：995 / 1003

页数：9

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