The crystal structure of K2[VO(C3H2O4)2H2O]•3H2O

被引：0

作者：

Filippova, IG ^{[1
]}

Kiosse, GA ^{[1
]}

机构：

[1] Moldavian Acad Sci, Inst Appl Phys, Chisinau, Moldova

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2000年 / 26卷 / 09期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of a binary malonate, K-2[VO(C3H2O4)(2)H2O]. 3H(2)O, is determined from 3486 unique reflections to R = 0.0496; a = 21.331(8), b = 13.793(7), c = 10.695(4) Angstrom, gamma = 69.16(3)degrees, Z = 8, space group P2(1)/b, rho(calcd) = 1.885(3) g/cm(3). The crystal is composed of the [VO(C3H2O4)(2)H2O](2-) complex anions, potassium cations, and solvate water molecules combined into a three-dimensional framework.

引用

页码：625 / 628

页数：4

共 15 条

[1]

ABLOV AV, 1975, ZH STRUKT KHIM, V16, P432

[2] SYNTHESIS AND STRUCTURAL STUDIES OF TETRAAQUACOPPER(II) DIAQUABIS(MALONATO)CUPRATE(II) [J].

CHATTOPADHYAY, D ;

CHATTOPADHYAY, SK ;

LOWE, PR ;

SCHWALBE, CH ;

MAZUMDER, SK ;

RANA, A ;

GHOSH, S .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (06) :913-916

[3]

DIMITROVA GI, 1974, DOKL AKAD NAUK SSSR+, V216, P1055

[4] CRYSTAL AND MOLECULAR STRUCTURE OF AMMONIUM VANADYL (+)-TARTRATE MONOHYDRATE [J].

FORREST, JG ;

PROUT, CK .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1967, (08) :1312-&

[5]

GAEDKOOP JA, 1957, ACTA CRYSTALLOGR, V10, P125

[6] VANADYL BOND-LENGTH VARIATIONS [J].

HON, PK ;

BELFORD, RL ;

PFLUGER, CE .

JOURNAL OF CHEMICAL PHYSICS, 1965, 43 (09) :3111-&

[7]

KIOSSE GA, 1989, DOKL AKAD NAUK SSSR+, V304, P607

[8] N,N,N',N'-TETRAMETHYLETHYLENEDIAMMONIUM AQUABIS(MALONATO)OXOVANADATE(IV) DIHYDRATE [J].

PAJUNEN, A ;

PAJUNEN, S .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1980, 36 (OCT) :2425-2428

[9]

PORAIKOSHITS MA, 1981, ITOGI NAUKI TEKHNI K, V15, P3

[10] ELECTRON SPIN RESONANCE IN COPPER(II) MALONATE [J].

RAJAN, R .

JOURNAL OF CHEMICAL PHYSICS, 1962, 37 (02) :460-&

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