In recent years, lignocellulosic biomass has gotten a lot of coverage, especially for the captured energy through the anaerobic degradation. The conversion of lignocellulosic biomass to biogas through an anaerobic digestion process has been facing challenges such as low biogas production, low buffering ability, poor end quality of products, and potential heterogeneity of biomass which have difficulties to define an optimized unit operation. These deficiencies may be related to the recalcitrant disposition of agricultural wastes or low mass transfer. India has a large amount of lignocellulosic biomass, and this biomass remains unused in the harvested field. However, it has a scope of utilization by conversion into useful biofuel. Furthermore, it could be enhanced the farmer's income as well as helps to contribute reduce the loss of environmental impact. Hence, the present review script discusses the potential, composition, biomethane production, pretreatment methods and technology related to lignocellulosic biomass, challenges, progress, and the latest program initiated in India. However, only 10 major types of lignocellulosic biomass have been reviewed in this paper.