共 59 条
Performance of magnesium oxide-coated bentonite in removal process of copper ions from aqueous solution
被引:42
作者:
Eren, E.
[1
]
Tabak, A.
[2
]
Eren, B.
[1
]
机构:
[1] Bilecik Univ, Fac Arts & Sci, Dept Chem, Bilecik, Turkey
[2] Rize Univ, Fac Arts & Sci, Dept Chem, Rize, Turkey
关键词:
Bentonite;
Adsorption;
Thermodynamic;
Clay;
Cu(II);
HEAVY-METAL IONS;
ADSORPTION CHARACTERISTICS;
MANGANESE;
PB(II);
CU(II);
EQUILIBRIUM;
LEAD(II);
EXCHANGE;
SORPTION;
IMMOBILIZATION;
D O I:
10.1016/j.desal.2010.02.028
中图分类号:
TQ [化学工业];
学科分类号:
0817 ;
摘要:
This paper presents the adsorption of Cu(II) ions from aqueous solution on modified Unye bentonite. Adsorption of Cu(II) ions by magnesium oxide-coated bentonite (MCB) sample was investigated as a function of the initial Cu (II) concentration, solution pH, ionic strength, temperature and inorganic ligands (Cl-, SO42-, and HPO42-). Changes in the surfaces and structure were characterized by means of XRD and N-2 gas adsorption data. The Langmuir monolayer adsorption capacity of MCB in 0.1 M KNO3 solution was estimated as 58.44 mg/g. Delta G, Delta H and Delta S values were evaluated for MCB to be -9.50 kJ/mol (at 303 K), 43.81 kJ/mol and 175.85 J/mol K. (C) 2010 Elsevier B.V. All rights reserved.
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页码:163 / 169
页数:7
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