Chromium terephthalate metal-organic framework MIL-101: synthesis, functionalization, and applications for adsorption and catalysis

被引：244

作者：

Bhattacharjee, Samiran ^{[1
]}

Chen, Chao ^{[1
,2
]}

Ahn, Wha-Seung ^{[1
]}

机构：

[1] Inha Univ, Dept Chem & Chem Engn, Inchon 402751, South Korea

[2] Xinyang Normal Univ, Coll Chem & Chem Engn, Xinyang 464000, Henan Province, Peoples R China

来源：

RSC ADVANCES | 2014年 / 4卷 / 94期

关键词：

LIQUID-CHROMATOGRAPHIC SEPARATION; HYDROGEN STORAGE PERFORMANCE; POROUS MATERIAL MIL-101(CR); HIGH PROTON CONDUCTIVITY; HIGH-SURFACE-AREA; ONE-POT SYNTHESIS; PD NANOPARTICLES; CARBON-DIOXIDE; CO2; CAPTURE; SELECTIVE OXIDATION;

D O I：

10.1039/c4ra11259h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The chromium terephthalate metal-organic framework, MIL-101 (MIL, Material Institut Lavoisier), is comprised of trimeric chromium(III) octahedral clusters interconnected by 1,4-benzenedicarboxylates, resulting in a highly porous 3-dimentional structure. The large pores (29 and 34 angstrom) and high BET surface area (>3000 m(2) g(-1)) with a huge cell volume (approximate to 702 000 angstrom(3)) together with the coordinatively unsaturated open metal sites that can be subjected to diverse post-synthesis functionalization or guest encapsulation, and excellent hydrothermal/chemical stability, make MIL-101 particularly attractive for applications, such as selective gas adsorption/separation, energy storage and heterogeneous catalysis. This paper reviews the current status of research and development on the synthesis, functionalization and applications of MIL-101 for adsorption/catalytic reactions.

引用

页码：52500 / 52525

页数：26

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