A ruthenium(II) complex with p-cymene and (S)-2-(anilinomethyl)pyrrolidine

被引：11
作者：
Aitali, M
El Firdoussi, L
Karim, A
Barrero, AF
Quirós, M [1 ]
机构：
[1] Univ Granada, Fac Ciencias, Dept Quim Inorgan, E-18071 Granada, Spain
[2] Fac Sci Semlalia, Chim Coordinat Lab, Marrakech, Morocco
[3] Univ Granada, Fac Ciencias, Dept Quim Organ, E-18071 Granada, Spain
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2000年 / 56卷
关键词：
D O I：
10.1107/S0108270100008787
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, [(S)-2-(anilinomethyl)pyrrolidine-N,N']chloro(eta(6) -para-cymene)ruthenium(II) chloride, [RuCl-(C10H14)(C11H16N2)]Cl, has been synthesized by the reaction of [RuCl2 (p-cymene)](2) (p-cymene is para-isopropyltoluene) with (S)-2-(anilinomethyl)pyrrolidine in triethylamine/2-propanol. The Ru atom is in a pseudo-tetrahedral environment coordinated by a chloride ligand, the aromatic hydrocarbon is linked in a eta(6) manner and the amine is linked via its two N atoms. The chloride anion is involved in hydrogen bonding with the diamine moieties through N-H ... Cl interactions, with N ... Cl distances of 3.273 (4) and 3.352 (4) Angstrom.
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页码：1088 / 1089
页数：2
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