Catalytic combustion of toluene over Mn, Fe and Co-exchanged clinoptilolite support

被引：52

作者：

Ozcelik, Zeynep ^{[1
]}

Soylu, Guelin S. Pozan ^{[1
]}

Boz, Ismail ^{[1
]}

机构：

[1] Istanbul Univ, Fac Engn, Dept Chem Engn, TR-34320 Istanbul, Turkey

来源：

CHEMICAL ENGINEERING JOURNAL | 2009年 / 155卷 / 1-2期

关键词：

Catalytic oxidation; Toluene; Transition metals; Clinoptilolite; Acidity; VOLATILE ORGANIC-COMPOUNDS; METAL CATALYSTS; OXIDE CATALYSTS; OXIDATION; ZEOLITES; PALLADIUM; REMOVAL; ACIDITY; IONS; VOCS;

D O I：

10.1016/j.cej.2009.07.013

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Catalytic combustion of toluene over Fe, Co, and Mn transition metal oxides catalysts supported on clinoptilolite (CLT) has been investigated. The catalysts have been characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), temperature-programmed reduction and oxidation (TPR/TPO) and thermogravimetric analysis (TGA). 9.5MnO(2)/NaCLT catalyst exhibited the catalytic activity, over which the toluene conversion reached to 93% at a temperature of 350 degrees C. The increase in activity was followed by increasing metal oxide content and gave a optimum at 9.5% MnO2 loading. Addition of metal oxide into clinoptilolite support led to a measurable decrease in the onset of combustion and an increase in toluene conversion. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：94 / 100

页数：7

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