Photo-degradation of curcumin in the presence of TiO2 nanoparticles: Fundamentals and application

被引：28

作者：

Singh, Umang ^{[1
]}

Verma, Sandeep ^{[1
]}

Ghosh, H. N. ^{[1
]}

Rath, M. C. ^{[1
]}

Priyadarsini, K. I. ^{[1
]}

Sharma, A. ^{[1
]}

Pushpa, K. K. ^{[1
]}

Sarkar, S. K. ^{[1
]}

Mukherjee, T. ^{[1
]}

机构：

[1] Bhabha Atom Res Ctr, Radiat & Photochem Div, Bombay 400085, Maharashtra, India

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2010年 / 318卷 / 1-2期

关键词：

Photo-degradation; Curcumin; Turmeric; TiO2; nanoparticles; CT complex; UV-vis light; ELECTRON-TRANSFER; SURFACE; STATE; DYE; DEGRADATION; DYNAMICS; METHANOL; SOLVENT;

D O I：

10.1016/j.molcata.2009.11.018

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Photo-degradation of curcumin in the presence of TiO2 nanoparticles has been Studied in water-methanol and water-aceronitrile mixed solvents. curcumin was found to form charge transfer(CT)complexes with TiO2 nanoparticles. The binding constant of the CT complexes has been determined. Curcumin was found to undergo photo-degradation under UV-vis and only visible light irradiations. Photo-degradation was investigated in the presence of external electron quenchers like methyl violegen and dissolved oxygen and hole quenchers like iodide ions in a de-aerated condition. The presence of oxygen was found to enhance the photo-degradation processes. The photo-degradation was found to be completely quenched in the presence of iodide ions in both the solvent mixtures in a de-aerated condition. A reaction pathway for the photo-degradation of curcumin in the presence of TiO2 nanoparticles has been proposed. This Study has been Successfully applied to remove the yellow turmeric stain from cotton fabrics. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：106 / 111

页数：6

共 30 条

[1] GGMS analysis of curcumin dye after selective degradation treatment [J].

Ahn, Cheunsoon ;

Obendorf, S. Kay .

FIBERS AND POLYMERS, 2007, 8 (03) :278-283

[2] EXCITED-STATE PROTON-TRANSFER REACTIONS .1. FUNDAMENTALS AND INTERMOLECULAR REACTIONS [J].

ARNAUT, LG ;

FORMOSINHO, SJ .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1993, 75 (01) :1-20

[3]

Atkins P., 2002, Physical Chemistry

[4] A SPECTROPHOTOMETRIC INVESTIGATION OF THE INTERACTION OF IODINE WITH AROMATIC HYDROCARBONS [J].

BENESI, HA ;

HILDEBRAND, JH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1949, 71 (08) :2703-2707

[5] Degradation of curcumin dye in aqueous solution and on Ag nanoparticles studied by ultraviolet-visible absorption and surface-enhanced Raman spectroscopy [J].

Canamares, M. V. ;

Garcia-Ramos, J. V. ;

Sanchez-Cortes, S. .

APPLIED SPECTROSCOPY, 2006, 60 (12) :1386-1391

[6]

Chattopadhyay I, 2004, CURR SCI INDIA, V87, P44

[7] Mechanistic studies of photocatalytic reaction of methanol for hydrogen production on Pt/TiO2 by in situ Fourier transform IR and time-resolved IR spectroscopy [J].

Chen, Tao ;

Feng, Zhaochi ;

Wu, Guopeng ;

Shi, Jianying ;

Ma, Guijun ;

Ying, Pinliang ;

Li, Can .

JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (22) :8005-8014

[8] Role of primary active species and TiO2 surface characteristic in UV-illuminated photodegradation of Acid Orange 7 [J].

Chen, YX ;

Yang, SY ;

Wang, K ;

Lou, LP .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2005, 172 (01) :47-54

[9]

Chopra R.N., 1958, INDIGENOUS DRUGS IND, Vsecond

[10] EXCITED-STATE PROTON-TRANSFER REACTIONS .2. INTRAMOLECULAR REACTIONS [J].

FORMOSINHO, SJ ;

ARNAUT, LG .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1993, 75 (01) :21-48

← 1 2 3 →