Polymer Single Crystal Templated Janus Nanoparticles

被引：55
作者：
Wang, Bingbing [1 ]
Li, Bing [1 ]
Ferrier, Robert C. M., Jr. [1 ]
Li, Christopher Y. [1 ]
机构：
[1] Drexel Univ, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2010年 / 31卷 / 02期
关键词：
block copolymers; nanoparticles; polymer brushes; polymer crystallization; polymer single crystals; SOLID-PHASE SYNTHESIS; GOLD NANOPARTICLES; CARBON NANOTUBES; ASYMMETRIC FUNCTIONALIZATION; SUPRAMOLECULAR CHEMISTRY; PARTICLES; NANOCRYSTALS; MICELLES; SCALE; AU;
D O I：
10.1002/marc.200900735
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Top-selective surface modification has been widely used for the synthesis of Janus nanoparticles (NPs). Herein we demonstrate that polymer single crystals can serve as generic substrates to immobilize NPs and the resultant NPs are Janus in nature. This technique is generic because various NPs as well as polymer single crystal substrates can be used. Single crystals of poly(ethylene oxide), polycaprolactone, and polyethylene-block-poly(ethylene oxide) have been successfully used to immobilize gold, magnetic, and semiconducting NPs. Subsequent dissolution of the single crystals led to various types of Janus NPs and NP clusters with different polymer brushes.
引用
收藏
页码：169 / 175
页数：7
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