Subsolidus binary phase diagram of C10Zn/C12Zn

被引：9

作者：

Wu, KZ ^{[1
]}

Zuo, P ^{[1
]}

Liu, XD ^{[1
]}

Li, YJ ^{[1
]}

机构：

[1] Hebei Normal Univ, Dept Chem, Shijiazhuang 050016, Hebei, Peoples R China

来源：

THERMOCHIMICA ACTA | 2003年 / 397卷 / 1-2期

关键词：

decylammonium tetrachlorozincate; dodecylammonium tetrachlorozincate; DSC; X-ray; phase diagram;

D O I：

10.1016/S0040-6031(02)00316-7

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Decylammonium tetrachlorozincate (n-C10H21NH3)(2)ZnCl4 (C10Zn) and dodecylammonium tetrachlorozincate (n-C12H25NH3)(2)ZnCl4 (C12Zn) were synthesized and a series of their mixtures C10Zn/C12Zn were prepared. The experimental binary phase diagram of C10Zn/Cl2Zn was established by means of differential scanning calorimetry (DSC) and X-ray diffraction. In the phase diagram a stable solid compound (n-C10H21NH3)(n-C12H25NH3)ZnCl4(C10C12Zn) and two eutectoid invariants were observed. It is noticeable that the phase diagram contains solid solution ranges. (C) 2002 Elsevier Science B.V All rights reserved.

引用

页码：49 / 53

页数：5

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