Synthesis of Homoleptic and Heteroleptic Bis-N-heterocylic Carbene Group 11 Complexes

被引：33

作者：

Lazreg, Faima ^{[1
]}

Cordes, David B. ^{[1
]}

Slawin, Alexandra M. Z. ^{[1
]}

Cazin, Catherine S. J. ^{[1
]}

机构：

[1] Univ St Andrews, EaStCHEM Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

ORGANOMETALLICS | 2015年 / 34卷 / 02期

基金：

英国工程与自然科学研究理事会;

关键词：

GOLD COMPLEXES; LIGANDS; SILVER(I); COPPER; HYDROSILYLATION; PHOSPHINE; NHC;

D O I：

10.1021/om500882t

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A straightforward synthetic route has been developed permitting the formation of homoleptic and heteroleptic bis-N-heterocyclic carbene metal complexes. The methodology has proven efficient for all group 11 members. These complexes are easily synthesized using [M(Cl)(NHC)] with different NHC salts in the presence of inexpensive bases such as sodium hydroxide. These systems were fully characterized and displayed high stability even in the presence of light.

引用

页码：419 / 425

页数：7

共 54 条

[51] Gold(I) N-heterocyclic carbene and carbazolate complexes [J].

Wang, HAJ ;

Vasam, CS ;

Tsai, TYR ;

Chen, SH ;

Chang, AHH ;

Lin, IJB .

ORGANOMETALLICS, 2005, 24 (04) :486-493

[52] Synthesis, structure, and spectroscopic properties of gold(I)-carbene complexes [J].

Wang, HMJ ;

Chen, CYL ;

Lin, IJB .

ORGANOMETALLICS, 1999, 18 (07) :1216-1223

[53] Facile synthesis of silver(I)-carbene complexes. Useful carbene transfer agents [J].

Wang, HMJ ;

Lin, IJB .

ORGANOMETALLICS, 1998, 17 (05) :972-975

[54] Cytotoxicity of Gold(I) N-Heterocyclic Carbene Complexes Assessed by Using Human Tumor Cell Lines [J].

Weaver, Jennifer ;

Gaillard, Sylvain ;

Toye, Caroline ;

Macpherson, Stephen ;

Nolan, Steven P. ;

Riches, Andrew .

CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (24) :6620-6624

← 1 2 3 4 5 6 →