Synthesis of Homoleptic and Heteroleptic Bis-N-heterocylic Carbene Group 11 Complexes

被引：33

作者：

Lazreg, Faima ^{[1
]}

Cordes, David B. ^{[1
]}

Slawin, Alexandra M. Z. ^{[1
]}

Cazin, Catherine S. J. ^{[1
]}

机构：

[1] Univ St Andrews, EaStCHEM Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

ORGANOMETALLICS | 2015年 / 34卷 / 02期

基金：

英国工程与自然科学研究理事会;

关键词：

GOLD COMPLEXES; LIGANDS; SILVER(I); COPPER; HYDROSILYLATION; PHOSPHINE; NHC;

D O I：

10.1021/om500882t

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A straightforward synthetic route has been developed permitting the formation of homoleptic and heteroleptic bis-N-heterocyclic carbene metal complexes. The methodology has proven efficient for all group 11 members. These complexes are easily synthesized using [M(Cl)(NHC)] with different NHC salts in the presence of inexpensive bases such as sodium hydroxide. These systems were fully characterized and displayed high stability even in the presence of light.

引用

页码：419 / 425

页数：7

共 54 条

[1] A STABLE CRYSTALLINE CARBENE
ARDUENGO, AJ
HARLOW, RL
KLINE, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (01) : 361 - 363
[2] HOMOLEPTIC CARBENE SILVER(I) AND CARBENE COPPER(I) COMPLEXES
ARDUENGO, AJ
DIAS, HVR
CALABRESE, JC
DAVIDSON, F
[J]. ORGANOMETALLICS, 1993, 12 (09) : 3405 - 3409
[3] First aryl-substituted acyclic imino-N-heterocyclic carbene ligand precursor: synthesis, characterisation and coordination with silver(I) and copper(I)
Badaj, Anna C.
Dastgir, Sarim
Lough, Alan J.
Lavoie, Gino G.
[J]. DALTON TRANSACTIONS, 2010, 39 (14) : 3361 - 3365
[4] Cationic, linear Au(I) N-heterocyclic carbene complexes:: synthesis, structure and anti-mitochondrial activity
Baker, Murray V.
Barnard, Peter J.
Berners-Price, Susan J.
Brayshaw, Simon K.
Hickey, James L.
Skelton, Brian W.
White, Allan H.
[J]. DALTON TRANSACTIONS, 2006, (30) : 3708 - 3715
[5] Dinuclear gold(I) complexes of bridging bidentate carbene ligands: synthesis, structure and spectroscopic characterisation
Barnard, PJ
Baker, MV
Berners-Price, SJ
Skelton, BW
White, AH
[J]. DALTON TRANSACTIONS, 2004, (07) : 1038 - 1047
[6] Carbene Transfer from Triazolylidene Gold Complexes as a Potent Strategy for Inducing High Catalytic Activity
Canseco-Gonzalez, Daniel
Petronilho, Ana
Mueller-Bunz, Helge
Ohmatsu, Kohsuke
Ooi, Takashi
Albrecht, Martin
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (35) : 13193 - 13203
[7] Carey F. A., 2001, ADV ORGANIC CHEM
[8] Cazin CSJ, 2011, CATAL MET COMPLEXES, V32, P1, DOI 10.1007/978-90-481-2866-2
[9] Percent buried volume for phosphine and N-heterocyclic carbene ligands: steric properties in organometallic chemistry
Clavier, Herve
Nolan, Steven P.
[J]. CHEMICAL COMMUNICATIONS, 2010, 46 (06) : 841 - 861
[10] Synthesis of well-defined N-heterocyclic carbene silver(I) complexes
de Frémont, P
Scott, NM
Stevens, ED
Ramnial, T
Lightbody, OC
Macdonald, CLB
Clyburne, JAC
Abernethy, CD
Nolan, SP
[J]. ORGANOMETALLICS, 2005, 24 (26) : 6301 - 6309

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