Formation of Ag/Al Screen-Printing Contacts on B Emitters

被引:48
作者
Fritz, Susanne [1 ]
Koenig, Markus [2 ]
Riegel, Stefanie [1 ]
Herguth, Axel [1 ]
Hoerteis, Matthias [2 ]
Hahn, Giso [1 ]
机构
[1] Univ Konstanz, Dept Phys, D-78464 Constance, Germany
[2] Heraeus Precious Met GmbH & Co KG, Elect Mat Div, Business Unit Photovolta, D-63450 Hanau, Germany
来源
IEEE JOURNAL OF PHOTOVOLTAICS | 2015年 / 5卷 / 01期
关键词
Boron emitters; contact formation; metallization; p(+) Si; scanning electron microscopy (SEM); screen-printing; METALLIZATION;
D O I
10.1109/JPHOTOV.2014.2364117
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
In this study, the contact formation process of Al containing Ag screen-printing pastes to BBr3-based B emitters on Si is investigated. Therefore, a detailed scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy study of top-view and cross-sectional samples was conducted. The possible influence of a SiNx:H antireflection coating was considered by comparing contacts with and without a SiNx:H layer. To analyze the role of the glass frit in the paste, the contact formation of pastes without glass was examined. The results indicate that the Ag/Al contact spots grow below the Si surface/SiNx:H layer. The glass frit is only indispensable for etching the antireflection layer-it is not needed for melting the metal in the screen-printing paste. The realized experiments lead to a phenomenological model for the contact formation process of Al containing screen-printing pastes to boron emitters.
引用
收藏
页码:145 / 151
页数:7
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