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Photocatalytic TiO2 thin films synthesized by the post-discharge of an RF atmospheric plasma torch
被引:25
|作者:
Collette, Stephanie
[1
]
Hubert, Julie
[1
]
Batan, Abdelkrim
[1
]
Baert, Kitty
[2
]
Raes, Marc
[2
]
Vandendael, Isabelle
[2
]
Daniel, Alain
[3
]
Archambeau, Catherine
[3
]
Terryn, Herman
[2
]
Reniers, Francois
[1
]
机构:
[1] Univ Libre Bruxelles, Serv Chim Analyt & Chim Interfaces CHANI, Blvd Triomphe 2, B-1050 Brussels, Belgium
[2] Vrije Univ Brussel, Dept Electrochem & Surface Engn SURF, Pl Laan 2, B-1050 Brussels, Belgium
[3] CRM Grp Adv Coatings & Construct Solut AC&CS, Quartier Polytech 3, Allee Innovat,1,B57, B-4000 Liege, Belgium
关键词:
Titanium dioxide;
Plasma deposition;
Atmospheric post-discharge;
Photocatalysis;
CHEMICAL-VAPOR-DEPOSITION;
TITANIUM-DIOXIDE;
METHYLENE-BLUE;
IN-SITU;
DEGRADATION;
BIOCOMPATIBILITY;
ANATASE;
HYDROPHILICITY;
ADSORPTION;
RUTILE;
D O I:
10.1016/j.surfcoat.2016.01.049
中图分类号:
TB3 [工程材料学];
学科分类号:
0805 ;
080502 ;
摘要:
Thin films of titanium oxide (TiO2) are synthesized at room temperature by the post-discharge of an RF atmospheric plasma torch supplied with argon and oxygen. Vapours of titanium tetraisopropoxide (TTIP) precursor are injected in the post-discharge by an argon flow rate bubbling in the liquid precursor. Without any external substrate heating, the coatings are amorphous and characterized by a thin film upon which agglomerates can be observed. The annealing of the coatings at 450 degrees C is efficient to (partially) crystallize the TiO2 since bands characteristic of the TiO2 anatase structure are observed in Raman spectra. The films are super-hydrophilic and present excellent photocatalytic activity; two properties of particular interest for self-cleaning applications. Nevertheless, annealed coating presents a higher photocatalytic activity. (C) 2016 Elsevier B.V. All rights reserved.
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页码:172 / 178
页数:7
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