The Mechanisms of Rectification in Au | Molecule | Au Devices Based on Langmuir-Blodgett Monolayers of Iron(III) and Copper(II) Surfactants

被引:26
作者
Wickramasinghe, Lanka D. [1 ]
Mazumder, Shivnath [1 ]
Gonawala, Sunalee [1 ]
Perera, Meeghage Madusanka [2 ]
Baydoun, Habib [1 ]
Thapa, Bishnu [1 ]
Li, Li [3 ]
Xie, Lingxiao [3 ]
Mao, Guangzhao [3 ]
Zhou, Zhixian [2 ]
Schlegel, H. Bernhard [1 ]
Verani, Claudio N. [1 ]
机构
[1] Wayne State Univ, Dept Chem, Detroit, MI 48202 USA
[2] Wayne State Univ, Dept Phys & Astron, Detroit, MI 48201 USA
[3] Wayne State Univ, Dept Chem Engn & Mat Sci, Detroit, MI 48202 USA
基金
美国国家科学基金会;
关键词
coordination chemistry; current rectification; device fabrication; electron transfer; molecular rectification; DENSITY-FUNCTIONAL THEORY; 5-COORDINATE IRON(III); ELECTRICAL RECTIFICATION; GALACTOSE-OXIDASE; CHARGE-TRANSPORT; COMPLEXES; SPECTROSCOPY; FILMS; VOLTAGE; POLYGLUTAMATES;
D O I
10.1002/anie.201408649
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Langmuir-Blodgett films of metallosurfactants were used in Au vertical bar molecule vertical bar Au devices to investigate the mechanisms of current rectification.
引用
收藏
页码:14462 / 14467
页数:6
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