Effects of Surfactants on the Rate of Chemical Reactions

被引：69
作者：
Samiey, B. [1 ]
Cheng, C. -H. [2 ]
Wu, J. [2 ]
机构：
[1] Lorestan Univ, Fac Sci, Dept Chem, Khorramabad 6813717133, Iran
[2] Ryerson Univ, Dept Chem Engn, Toronto, ON M5B 2K3, Canada
来源：
JOURNAL OF CHEMISTRY | 2014年 / 2014卷
关键词：
DIELS-ALDER REACTIONS; LATENT POLYPHENOL OXIDASE; SODIUM DODECYL-SULFATE; P-NITROPHENYL ACETATE; ALKALINE-HYDROLYSIS; ELECTRON-TRANSFER; AQUEOUS ACID; HEAD GROUP; NUCLEOPHILIC-SUBSTITUTION; EMULSION POLYMERIZATION;
D O I：
10.1155/2014/908476
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Surfactants are self-assembled compounds that depend on their structure and electric charge can interact as monomer or micelle with other compounds (substrates). These interactions which may catalyze or inhibit the reaction rates are studied with pseudophase, cooperativity, and stoichiometric (classical) models. In this review, we discuss applying these models to study surfactant-substrate interactions and their effects on Diels-Alder, redox, photochemical, decomposition, enzymatic, isomerization, ligand exchange, radical, and nucleophilic reactions.
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页数：14
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