Copper(I)-mediated carboamination of vinyl azides by aryldiazonium salts: synthesis of N2-substituted 1,2,3-triazoles

被引：44

作者：

Liu, Zhenhua ^{[1
]}

Ji, Huimin ^{[1
]}

Gao, Wen ^{[1
]}

Zhu, Guangyu ^{[1
]}

Tong, Lili ^{[1
]}

Lei, Fengcai ^{[1
]}

Tang, Bo ^{[1
]}

机构：

[1] Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Collaborat Innovat Ctr Functionalized Probes Chem, Key Lab Mol & Nano Probes,Minist Educ,Inst Biomed, Jinan 250014, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 46期

基金：

中国国家自然科学基金;

关键词：

TERMINAL ALKYNES; CLICK CHEMISTRY; CATALYZED ARYLATION; DIAZONIUM SALTS; BOND-CLEAVAGE; TRIAZO-GROUP; H ARYLATION; PALLADIUM; ALKENES; CYCLOADDITION;

D O I：

10.1039/c7cc02391j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A copper(I)-mediated carboamination cascade reaction between vinyl azides and aryldiazonium salts is described. Functionally diverse N-2-substituted 1,2,3-triazoles were obtained in moderate to good yields through novel difunctionalization of vinyl azides by aryldiazonium salt sources. This method has a wide scope, good functional-group tolerance and insensitivity to an ambient atmosphere.

引用

收藏

页码：6259 / 6262

页数：4

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