catena-Poly[[[μ-pyridinium-3-carboxylato-bis[dioxomolybdenum(VI)]]-di-μ3-oxo] monohydrate]

被引:20
作者
Chen, SM [1 ]
Lu, CZ [1 ]
Yu, YQ [1 ]
Zhang, QZ [1 ]
He, X [1 ]
机构
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, Natl Ctr Nanosci & Nanotechnol, State Key Lab Struct Chem, Fujian 350002, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2004年 / 60卷
关键词
D O I
10.1107/S0108270104016944
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel chain molybdenum compound, {[Mo2O6(C6H5NO2)].H2O}(n), which was synthesized under hydrothermal conditions, consists of an infinite rail-like chain formed by molybdenum oxide units linked by zwitterionic nicotinic acid ligands. Each Mo atom is coordinated octahedrally by six O atoms and the MoO6 octahedra are linked to one another via edge-sharing to produce a zigzag polymeric chain, with nicotinic acid ligands located, alternately, on each side of the rail-like chain plane.
引用
收藏
页码:M437 / M439
页数:3
相关论文
共 11 条
  • [11] TIMOTHY PB, 1988, INORG CHEM, V27, P2059