catena-Poly[[[μ-pyridinium-3-carboxylato-bis[dioxomolybdenum(VI)]]-di-μ3-oxo] monohydrate]

被引：20

作者：

Chen, SM ^{[1
]}

Lu, CZ ^{[1
]}

Yu, YQ ^{[1
]}

Zhang, QZ ^{[1
]}

He, X ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, Natl Ctr Nanosci & Nanotechnol, State Key Lab Struct Chem, Fujian 350002, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2004年 / 60卷

关键词：

D O I：

10.1107/S0108270104016944

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel chain molybdenum compound, {[Mo2O6(C6H5NO2)].H2O}(n), which was synthesized under hydrothermal conditions, consists of an infinite rail-like chain formed by molybdenum oxide units linked by zwitterionic nicotinic acid ligands. Each Mo atom is coordinated octahedrally by six O atoms and the MoO6 octahedra are linked to one another via edge-sharing to produce a zigzag polymeric chain, with nicotinic acid ligands located, alternately, on each side of the rail-like chain plane.

引用

页码：M437 / M439

页数：3

共 11 条

[1] Ferrimagnetic-like ordering in a unique three-dimensional coordination polymer featuring mixed azide/carboxylate-bridged trinuclear manganese(II) clusters as subunits
Chen, HJ
Mao, ZW
Gao, S
Chen, XM
[J]. CHEMICAL COMMUNICATIONS, 2001, (22) : 2320 - 2321
[2] 2 DIMOLYBDENUM TETRACARBOXYLATE COMPOUNDS FROM HETEROAROMATIC ACIDS, 2-THIOPHENECARBOXYLATE AND NICOTINIC-ACID
COTTON, FA
FALVELLO, LR
REID, AH
ROTH, WJ
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1990, 46 : 1815 - 1818
[3] 'Adding' stable functional complementary, nucleophilic and electrophilic clusters:: a synthetic route to [{(SiW11O39)Mo3S4(H2O)3(μ-OH)}2]10- and [{(P2W17O61)Mo3S4(H2O)3(μ-OH)}2]14- as examples
Müller, A
Fedin, VP
Kuhlmann, C
Fenske, HD
Baum, G
Bögge, H
Hauptfleisch, B
[J]. CHEMICAL COMMUNICATIONS, 1999, (13) : 1189 - 1190
[4] From simple building blocks to structures with increasing size and complexity
Müller, A
Kögerler, P
[J]. COORDINATION CHEMISTRY REVIEWS, 1999, 182 : 3 - 17
[5] POLYOXOMETALATE CHEMISTRY - AN OLD FIELD WITH NEW DIMENSIONS IN SEVERAL DISCIPLINES
POPE, MT
MULLER, A
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (01): : 34 - 48
[6] Hydrothermal synthesis and structural characterization of an organic-inorganic hybrid material:: (H2tptz)2[δ-Mo8O26]•2H2O (tptz=2,4,6-tripyridyltriazine)
Rarig, RS
Zubieta, J
[J]. INORGANICA CHIMICA ACTA, 2001, 312 (1-2) : 188 - 196
[7] Sheldrick G.M., 1996, SADABS VERSION 2008
[8] *SIEM AN XRAY INST, 1994, SAINT SHELXTL VERS 5
[9] *SIEM AN XRAY INST, 1996, SMART VERS 4 0
[10] Strukan N, 2000, ACTA CRYSTALLOGR C, V56, P639

← 1 2 →