Monodentate N-coordination of a 1,2,3,5-dithiadiazolyl to Mn(II), Co(II) and Ni(II): A new coordination mode

被引：24

作者：

Hearns, Nigel G. R.

Hesp, Kevin D.

Jennings, Michael

Korcok, Jasmine L.

Preuss, Kathrvn E. ^{[1
]}

Smithson, Chad S.

机构：

[1] Univ Guelph, Dept Chem, Guelph, ON N1G 2W1, Canada

[2] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada

来源：

POLYHEDRON | 2007年 / 26卷 / 9-11期

基金：

加拿大自然科学与工程研究理事会;

关键词：

metal coordination; dithiadiazolyl; thiazyl; crystal structure;

D O I：

10.1016/j.poly.2006.09.078

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of neutral radical ligand 4-(2 '-cyanofuryl-5 ')-1,2,3,5-dithiadiazolyI with a stoichiometric amount of bis(hexafluoroacetylacetonato)-manganese(II), -cobalt(II) or nickel(II) generates alternating metal-ligand chains in the solid state. The coordination mode of this ligand to the metal dication is unprecedented, providing the first evidence that the nitrogen atoms of a 1,2,3,5-dithiadiazolyl are capable of coordination to a metal dication in the absence of chelation. (c) 2006 Elsevier Ltd. All rights reserved.

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页码：2047 / 2053

页数：7

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