RAFT inverse miniemulsion polymerization of acrylamide

被引：49
|
作者：
Qi, Genggeng
Jones, Christopher W.
Schork, F. Joseph
机构：
[1] Georgia Inst Technol, Sch Chem & Biomol Engn, Atlanta, GA 30332 USA
[2] Univ Maryland, Dept Chem & Biomol Engn, College Pk, MD 20742 USA
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2007年 / 28卷 / 09期
基金：
美国国家科学基金会;
关键词：
aqueous polymerization; inverse miniemulsion; living polymerization; poly(acrylamide); reversible addition fragmentation chain transfer (RAFT);
D O I：
10.1002/marc.200700026
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
RAFT inverse miniemulsion polymerization is demonstrated for the first time as an alternate way to synthesize hydrophilic polymer latexes. The kinetic behavior of inverse RAFT miniemulsion polymerization of acrylamide is similar to that observed in aqueous RAFT solution polymerization. A water-soluble initiator provides better control than a lipophilic initiator in inverse RAFT miniemulsion polymerization under the conditions used here.
引用
收藏
页码：1010 / 1016
页数：7
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