Enzymatic ring-opening polymerization of oxiranes and dicarboxylic anhydrides

被引：21

作者：

Soeda, Y ^{[1
]}

Okamoto, T ^{[1
]}

Toshima, K ^{[1
]}

Matsumura, S ^{[1
]}

机构：

[1] Keio Univ, Fac Sci & Technol, Dept Appl Chem, Kohoku Ku, Yokohama, Kanagawa 2238522, Japan

来源：

MACROMOLECULAR BIOSCIENCE | 2002年 / 2卷 / 09期

关键词：

dicarboxylic anhydride; enzymes; oxirane; polyesters; polyethers;

D O I：

10.1002/mabi.200290003

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Oxiranes, such as glycidylphenyl ether, benzyl glycidate, glycidyl methyl ether, and styrene oxide, were copolymerized with dicarboxylic anhydrides, such as succinic anhydride, phthalic anhydride, and maleic anhydride by the action of an enzyme in a stepwise reaction to produce the corresponding polyesters containing some ether linkages having a maximum (M) over bar (w) of 13 500. Oxiranes such as glycidol and glycidyl phenyl ether were also homopolymerized and copolymerized with other oxirane by the enzyme to produce the corresponding polyethers.

引用

页码：429 / 436

页数：8

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