Polymeric carbon nitride (C3N4) as heterogeneous photocatalyst for selective oxidation of alcohols to aldehydes

被引：57
作者：
Marci, G. [1 ]
Garcia-Lopez, E., I [1 ]
Palmisano, L. [1 ]
机构：
[1] Univ Palermo, Dipartimento Energia Ingn Informaz & Modelli Mate, Schiavello Grillone Photocatalysis Grp, Viale Sci, I-90128 Palermo, Italy
来源：
CATALYSIS TODAY | 2018年 / 315卷
关键词：
Carbon nitride; C3N4; 2D-material; Photocayalysis; Polymeric photocatalyst; Selective photo-oxidation; Partial oxidation; Alcohol; VISIBLE-LIGHT PHOTOCATALYSIS; METAL-FREE G-C3N4; AROMATIC ALCOHOLS; ARTIFICIAL PHOTOSYNTHESIS; AEROBIC OXIDATION; BENZYL ALCOHOL; WATER; ACTIVATION; NANOSHEETS; REDUCTION;
D O I：
10.1016/j.cattod.2018.03.038
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Polymeric carbon nitride (C3N4) is a semiconductor material which is a very promising green photocatalyst with good physico-chemical properties and stability. It is a metal-free carbon based non-toxic material which can be easily obtained from earth-abundant components. The robustness and versatility of C3N4 as a photo-redox catalyst allows its use for selective oxidations by heterogeneous photocatalysis. This paper reviews the state of art in the application of C3N4 as heterogeneous photocatalyst for selective oxidation of alcohols to the corresponding aldehydes.
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收藏
页码：126 / 137
页数：12
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