Benzylic oxidation and photooxidation by air in the presence of graphite and cyclohexene

被引：14

作者：

Sereda, Grigoriy ^{[1
]}

Rajpara, Vikul ^{[1
]}

机构：

[1] Univ S Dakota, Dept Chem, Vermillion, SD 57069 USA

来源：

TETRAHEDRON LETTERS | 2007年 / 48卷 / 19期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/j.tetlet.2007.03.072

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Graphite is introduced as a convenient catalyst for cyclohexene-promoted photooxidation of p-xylene, ethylbenzene, and cumene by air. Availability of the reagent (air), lack of chemical waste, low toxicity, and reusability of the catalyst make the process a good green alternative of oxidation of these industrially important hydrocarbons. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：3417 / 3421

页数：5

共 19 条

[1]

BREITMAIER E, 2005, ORG MAGN RESONANCE, V8, P573

[2]

Bürgstein MR, 2001, CHEM-EUR J, V7, P3078, DOI 10.1002/1521-3765(20010716)7:14<3078::AID-CHEM3078>3.0.CO

[3]

2-E

[4]

CHE ZJ, 2006, Patent No. 200510112782005