Particle morphology characterization and magnetic properties of LaMnO3+d perovskites

被引:12
作者
Popa, M
Van Hong, L
Kakihana, M
机构
[1] Tokyo Inst Technol, Mat & Struct Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
[2] Inst Sci Mat, Hanoi, Vietnam
关键词
LaMnO3+d; polymerizable complex method; ferromagnetism;
D O I
10.1016/S0921-4526(02)01737-4
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
In this research we report the characterization of LaMnO3 + d powders synthesized by the polymerized complex method based on the Pechini-type reaction. High-quality nanopowders with controlled stoichiometry and microstructure were prepared at 700degreesC, with mean particle sizes of approximately 45 nm. The synthesized materials were characterized by X-ray diffraction. The structure, homogeneity and particle size of the obtained compounds during different stages were investigated by scanning electron microscopy. The surface area of the final powders was determined, and the thermal magnetization curves in the range 100-300 K were analyzed. The magnetization curves indicated the ferromagnetic behavior of the powders. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:237 / 240
页数:4
相关论文
共 14 条
[1]   RELATIONSHIP BETWEEN CRYSTAL SYMMETRY AND MAGNETIC PROPERTIES OF IONIC COMPOUNDS CONTAINING MN3 [J].
GOODENOUGH, J ;
ARNOTT, RJ ;
MENYUK, N ;
WOLD, A .
PHYSICAL REVIEW, 1961, 124 (02) :373-&
[2]   Synthesis and spectroscopic characterisation of Y-doped Cd2SnO4 [J].
Gulino, A ;
Fragalà, I .
JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (11) :2837-2841
[3]   FERROMAGNETIC COMPOUNDS OF MANGANESE WITH PEROVSKITE STRUCTURE [J].
JONKER, GH ;
VANSANTEN, JH .
PHYSICA, 1950, 16 (03) :337-349
[4]   The origin of ferromagnetism in LaMnO3+δ [J].
Joy, PA ;
Sankar, CR ;
Date, SK .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2002, 14 (19) :4985-4993
[5]   Synthesis of high surface area LaMnO3+d by a polymerizable complex method [J].
Kakihana, M ;
Arima, M ;
Yoshimura, M ;
Ikeda, N ;
Sugitani, Y .
JOURNAL OF ALLOYS AND COMPOUNDS, 1999, 283 (1-2) :102-105
[6]   ''Sol-Gel'' preparation of high temperature superconducting oxides [J].
Kakihana, M .
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 1996, 6 (01) :7-55
[7]   Dramatic change in magnetic properties of manganates Ca2-xLnxMnO4 by low-temperature electrochemical oxidation in fused nitrates [J].
Michel, CR ;
Amigó, R ;
Casañ-Pastor, N .
CHEMISTRY OF MATERIALS, 1999, 11 (02) :195-197
[8]   Characterization of LaMeO3 (Me: Mn, Co, Fe) perovskite powders obtained by polymerizable complex method [J].
Popa, M ;
Frantti, J ;
Kakihana, M .
SOLID STATE IONICS, 2002, 154 :135-141
[9]   Observation of antiferromagnetic domains in epitaxial thin films [J].
Scholl, A ;
Stöhr, J ;
Lüning, J ;
Seo, JW ;
Fompeyrine, J ;
Siegwart, H ;
Locquet, JP ;
Nolting, F ;
Anders, S ;
Fullerton, EE ;
Scheinfein, MR ;
Padmore, HA .
SCIENCE, 2000, 287 (5455) :1014-1016
[10]   OXIDATIVE NONSTOICHIOMETRY IN PEROVSKITES, AN EXPERIMENTAL SURVEY - DEFECT STRUCTURE OF AN OXIDIZED LANTHANUM MANGANITE BY POWDER NEUTRON-DIFFRACTION [J].
TOFIELD, BC ;
SCOTT, WR .
JOURNAL OF SOLID STATE CHEMISTRY, 1974, 10 (03) :183-194