Urban VOC profiles, possible sources, and its role in ozone formation for a summer campaign over Xi'an, China

To insight the urban volatile organic compound (VOC) profiles and its contribution to ozone, four-time per day (8:00-9:00, 15:00-16:00, 19:00-20:00, and 23:00-24:00) off-line VOC samples were collected from 16th July to 28th July 2018 for a summer investigation campaign over Xi'an, China. The diurnal variation was significant that the lowest TVOC concentrations were observed in the midnight period (28.4 +/- 25.6 ppbv) while the highest was shown in the morning (49.6 +/- 40.1 ppbv). The differences of total non-methane VOCs (TVOCs) between weekdays and weekend were also significant that the weekend showed significantly high VOC levels than weekdays (p < 0.05) but did not lead to significant ambient O-3 increase (p > 0.05). Isopentane, a general marker for vehicle exhaust, showed descending concentrations from morning to midnight and good correlation with vehicle numbers on road, indicating a potential source to the VOCs at this site. The results from PMF proved that vehicular exhaust was the largest source to the VOCs in this study (64.4%). VOC categories showed a reverse sequence in abundance of concentrations and OFP contributions that alkenes showed the highest OFPs although with the lowest abundance in TOVCs due to their high reactivity in photochemical reactions. High OFPs from ethylene and isopentane indicated that vehicular emissions could be the largest potential OFP source in this site. OFPs from isoprene (from 1.85 to 13.4 ppbv) indicated that biogenic VOCs should not be negligible in urban Xi'an city when controlling O-3 pollutants. Comparison of two OFP methods was conducted and MIR method was proved to be more reasonable and scientific in summer Xi'an. Therefore, vehicular emission, the largest contributor to ambient VOCs and also OFPs, as well as biological source should be priority controlled in guiding VOC emissions and reducing O-3 control policies.