Chiral Ionic Liquid Monolayer-Stabilized Gold Nanoparticles: Synthesis, Self-Assembly, and Application to SERS

被引:40
作者
Bai, Xiangtao [1 ]
Li, Xinwei [1 ]
Zheng, Liqiang [1 ]
机构
[1] Shandong Univ, Minist Educ, Key Lab Colloid & Interface Chem, Jinan 250100, Peoples R China
基金
中国国家自然科学基金;
关键词
SUPRAMOLECULAR CHEMISTRY; LANGMUIR MONOLAYERS; AU NANOPARTICLES; SURFACE; FABRICATION; NANORODS; SYSTEMS; ORIGIN; WATER;
D O I
10.1021/la101602a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Chiral ionic liquid monolayer-stabilized gold nanoparticles were synthesized in a two-phase liquid liquid system and found to self-assemble into ringlike structures at the air/water interface. Control experiments with long-chain ILs revealed that the molecular structure of the CIL significantly affects the formation of the gold nanoparticle ring structures. A possible mechanism based on Marangoni-Benard convection in evaporating droplets was proposed. These gold nanoparticle structures were shown to yield a large SERS enhancement for Rhodamine 6G.
引用
收藏
页码:12209 / 12214
页数:6
相关论文
共 60 条
[1]   STRIPE PATTERNS FORMED ON A GLASS-SURFACE DURING DROPLET EVAPORATION [J].
ADACHI, E ;
DIMITROV, AS ;
NAGAYAMA, K .
LANGMUIR, 1995, 11 (04) :1057-1060
[2]   Synthesis and characterization of microscale gold nanoplates using Langmuir monolayers of long-chain ionic liquid [J].
Bai, Xiangtao ;
Zheng, Liqiang ;
Li, Na ;
Dong, Bin ;
Liu, Hongguo .
CRYSTAL GROWTH & DESIGN, 2008, 8 (10) :3840-3846
[3]   Optical enhancing properties of anisotropic gold nanoplates prepared with different fractions of a natural humic substance [J].
Baigorri, Roberto ;
Garcia-Mina, Jose M. ;
Aroca, Ricardo F. ;
Alvarez-Puebla, Ramon A. .
CHEMISTRY OF MATERIALS, 2008, 20 (04) :1516-1521
[4]   Synthesis of chiral ionic liquids from natural amino acids [J].
Bao, WL ;
Wang, ZM ;
Li, YX .
JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (02) :591-593
[5]   Nanoscale insights in the creation and transfer of chirality in amino acid monolayers at defined metal surfaces [J].
Barlow, S. M. ;
Raval, R. .
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2008, 13 (1-2) :65-73
[6]   SYNTHESIS OF THIOL-DERIVATIZED GOLD NANOPARTICLES IN A 2-PHASE LIQUID-LIQUID SYSTEM [J].
BRUST, M ;
WALKER, M ;
BETHELL, D ;
SCHIFFRIN, DJ ;
WHYMAN, R .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (07) :801-802
[7]   A new peptide-based method for the design and synthesis of nanoparticle superstructures: Construction of highly ordered gold nanoparticle double helices [J].
Chen, Chun-Long ;
Zhang, Peijun ;
Rosi, Nathaniel L. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (41) :13555-+
[8]   A facile solution chemical route to self-assembly of CuS ball-flowers and their application as an efficient photocatalyst [J].
Cheng, Zhiguo ;
Wang, Shaozhen ;
Wang, Qian ;
Geng, Baoyou .
CRYSTENGCOMM, 2010, 12 (01) :144-149
[9]   Gold nanoparticles: Assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology [J].
Daniel, MC ;
Astruc, D .
CHEMICAL REVIEWS, 2004, 104 (01) :293-346
[10]   The self-assembly, characterization and application of hemoglobin immobilized on Fe3O4@Pt core-shell nanoparticles [J].
Fan, Hong ;
Pan, Zhong-Qin ;
Gu, Hai-Ying .
MICROCHIMICA ACTA, 2010, 168 (3-4) :239-244