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The influence of surface lubricity on the adhesion of Navicula perminuta and Ulva linza to alkanethiol self-assembled monolayers
被引:42
作者:
Bowen, J.
Pettitt, M. E.
Kendall, K.
Leggett, G. J.
Preece, J. A.
Callow, M. E.
Callow, J. A.
[1
]
机构:
[1] Univ Birmingham, Sch Biosci, Birmingham B15 2TT, W Midlands, England
[2] Univ Birmingham, Sch Chem, Birmingham B15 2TT, W Midlands, England
[3] Univ Birmingham, Sch Chem Engn, Birmingham B15 2TT, W Midlands, England
[4] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England
关键词:
adhesion;
biofouling;
alkanethiol;
self-assembled monolayer;
Ulva;
Navicula;
D O I:
10.1098/rsif.2006.0191
中图分类号:
O [数理科学和化学];
P [天文学、地球科学];
Q [生物科学];
N [自然科学总论];
学科分类号:
07 ;
0710 ;
09 ;
摘要:
The settlement and adhesion of Navicula perminuta and Ulva linza to methyl-terminated alkanethiol self-assembled monolayers (SAMs) of increasing chain length has been investigated. Organisms were allowed to settle onto the monolayers and were subsequently exposed to hydrodynamic shear stress in order to determine their adhesion strength. Results show that as the SAM structure changes from amorphous to crystalline (C14), there is a marked change in the adhesion of N. perminuta and U. linza. Given that the SAMs in the series all exhibit similar contact angle behaviour and surface energy, it is hypothesized that the lubricity of the surface plays a role in determining the surface adhesion.
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页码:473 / 477
页数:5
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