Formation and corrosion properties of Fe-based bulk metallic glasses

被引:0
作者
Zhu, Chun-lei [1 ]
Wang, Qing [1 ]
Zhang, Jie [1 ]
Wang, Ying-min [1 ]
Dong, Chuang [1 ]
机构
[1] Dalian Univ Technol, Sch Mat Sci & Engn, Dalian 116024, Peoples R China
基金
中国国家自然科学基金;
关键词
bulk metallic glasses (BMG); cluster; atomic cluster; corrosion; glass-forming ability; FORMING ABILITY; ALLOYS; CRITERION;
D O I
10.1007/s12613-010-0312-x
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Bulk metallic glass (BMG) formation was explored in the Fe-B-Si-Nb alloy system though combined use of the atomic cluster line approach and the minor alloying strategy. The basic ternary compositions in the Fe-B-Si system were determined by the intersection points of two cluster lines, namely, Fe-B cluster to Si and Fe-Si cluster to B. 3at%-4at% Nb was added to the quaternary Fe-B-Si-Nb alloy. The casting experiments revealed that good glass-forming ability (GFA) occurred at the (Fe73.4Si8.2B18.4)(96)Nb-4 composition, and 3-mm diameter BMG samples were made. The glass transition temperature (T-g), crystallization temperature (T-x), and supercooled liquid region (Delta T-x=T-x-T-g) of this BMG were measured to be 866, 889, and 23 K, respectively. The BMG shows a high Vickers hardness of about Hv 1164, a Young's modulus of 180 GPa, and a good corrosion resistance in the solutions of 1 mol/L HCl and 3wt% NaCl.
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页码:323 / 326
页数:4
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