Supramolecular self-assembly of three-dimensional polyaniline and polypyrrole crystals

被引:20
作者
Tao, Yulun [1 ,2 ]
Li, Juchuan [3 ]
Xie, Anjian [1 ]
Li, Shikuo [1 ]
Chen, Ping [1 ]
Ni, Liping [1 ]
Shen, Yuhua [1 ]
机构
[1] Anhui Univ, Sch Chem & Chem Engn, Hefei 230039, Peoples R China
[2] Anhui Univ Sci & Technol, Dept Mat Sci & Engn, Huainan 232001, Peoples R China
[3] Univ Kentucky, Dept Chem & Mat Engn, Lexington, KY 40506 USA
基金
中国国家自然科学基金;
关键词
D O I
10.1039/c4cc05559d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Herein, we first report a novel approach for preparing 3D pi-pi stacked crystals of polyaniline and polypyrrole and show how they self-assemble in a suitable solution environment. 3D crystals of polyaniline and polypyrrole show high charge-transport properties of 130 S cm(-1) and 150 S cm(-1), respectively. Remarkably, the 3D crystals of polyaniline obtain excellent anisotropic conductivity.
引用
收藏
页码:12757 / 12760
页数:4
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