The effect of molecular conformation on single molecule conductance:: measurements of π-conjugated oligoaryls by STM break junction

被引:25
作者
Chen, I-Wen Peter
Fu, Ming-Dung
Tseng, Wei-Hsiang
Chen, Chun-Hsien [1 ]
Chou, Chih-Ming
Luh, Tien-Yau
机构
[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 30013, Taiwan
[2] Natl Taiwan Univ, Dept Chem, Taipei 10617, Taiwan
关键词
D O I
10.1039/b705521h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Measurements of molecular break junction reveal quantitatively the correlation betweeen the single-molecule conductance and the conformation of pi-conjugated molecules with 6 - 18 conjugated double bonds.
引用
收藏
页码:3074 / 3076
页数:3
相关论文
共 32 条
[1]   Charge transfer on the nanoscale: Current status [J].
Adams, DM ;
Brus, L ;
Chidsey, CED ;
Creager, S ;
Creutz, C ;
Kagan, CR ;
Kamat, PV ;
Lieberman, M ;
Lindsay, S ;
Marcus, RA ;
Metzger, RM ;
Michel-Beyerle, ME ;
Miller, JR ;
Newton, MD ;
Rolison, DR ;
Sankey, O ;
Schanze, KS ;
Yardley, J ;
Zhu, XY .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (28) :6668-6697
[2]   Interface geometry and molecular junction conductance: Geometric fluctuation and stochastic switching [J].
Basch, H ;
Cohen, R ;
Ratner, MA .
NANO LETTERS, 2005, 5 (09) :1668-1675
[3]   Effect of anchoring groups on single-molecule conductance: Comparative study of thiol-, amine-, and carboxylic-acid-terminated molecules [J].
Chen, Fang ;
Li, Xiulan ;
Hihath, Joshua ;
Huang, Zhifeng ;
Tao, Nongjian .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (49) :15874-15881
[4]   Conductance and stochastic switching of ligand-supported linear chains of metal atoms [J].
Chen, I-Wen Peter ;
Fu, Ming-Dung ;
Tseng, Wei-Hsiang ;
Yu, Jian-Yuan ;
Wu, Sung-Hsun ;
Ku, Chia-Jui ;
Chen, Chun-hsien ;
Peng, Shie-Ming .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (35) :5814-5818
[5]   Convergent/divergent synthesis and photophysical studies of alternating benzene-furan oligoaryls from substituted propargylic dithioacetals [J].
Chou, Chih-Ming ;
Chen, Wei-Qiang ;
Chen, Jia-Hong ;
Lin, Cheng-Lan ;
Tseng, Jui-Chang ;
Lee, Chin-Fa ;
Luh, Tien-Yau .
CHEMISTRY-AN ASIAN JOURNAL, 2006, 1 (1-2) :46-55
[6]   Reproducible measurement of single-molecule conductivity [J].
Cui, XD ;
Primak, A ;
Zarate, X ;
Tomfohr, J ;
Sankey, OF ;
Moore, AL ;
Moore, TA ;
Gust, D ;
Harris, G ;
Lindsay, SM .
SCIENCE, 2001, 294 (5542) :571-574
[7]   Conductance switching in single molecules through conformational changes [J].
Donhauser, ZJ ;
Mantooth, BA ;
Kelly, KF ;
Bumm, LA ;
Monnell, JD ;
Stapleton, JJ ;
Price, DW ;
Rawlett, AM ;
Allara, DL ;
Tour, JM ;
Weiss, PS .
SCIENCE, 2001, 292 (5525) :2303-2307
[8]   Currents through single molecular junction of Au/hexanedithiolate/Au measured by repeated formation of break junction in STM under UHV: Effects of conformational change in an alkylene chain from gauche to trans and binding sites of thiolates on gold [J].
Fujihira, Masamichi ;
Suzuki, Masaaki ;
Fujii, Shintaro ;
Nishikawa, Ayano .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2006, 8 (33) :3876-3884
[9]   Thermal gating of the single molecule conductance of alkanedithiols [J].
Haiss, W ;
van Zalinge, H ;
Bethell, D ;
Ulstrup, J ;
Schiffrin, DJ ;
Nichols, RJ .
FARADAY DISCUSSIONS, 2006, 131 :253-264
[10]   Electronic decay constant of carotenoid polyenes from single-molecule measurements [J].
He, J ;
Chen, F ;
Li, J ;
Sankey, OF ;
Terazono, Y ;
Herrero, C ;
Gust, D ;
Moore, TA ;
Moore, AL ;
Lindsay, SM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (05) :1384-1385