Excellent energy storage density and efficiency in blend polymer-based composites by design of core-shell structured inorganic fibers and sandwich structured films

被引：103
作者：
Cui, Yang [1 ,2 ]
Zhang, Tiandong [1 ,2 ]
Feng, Yu [1 ,2 ]
Zhang, Changhai [1 ,2 ]
Chi, Qingguo [1 ,2 ,3 ]
Zhang, Yongquan [1 ,2 ]
Chen, Qingguo [1 ,2 ]
Wang, Xuan [1 ,2 ]
Lei, Qingquan [1 ,2 ]
机构：
[1] Harbin Univ Sci & Technol, Key Lab Engn Dielect & Its Applicat, Minist Educ, Harbin 150080, Heilongjiang, Peoples R China
[2] Harbin Univ Sci & Technol, Sch Elect & Elect Engn, Harbin 150080, Heilongjiang, Peoples R China
[3] Univ Elect Sci & Technol China, State Key Lab Elect Thin Films & Integrated Devic, Chengdu 610054, Sichuan, Peoples R China
来源：
COMPOSITES PART B-ENGINEERING | 2019年 / 177卷
基金：
中国博士后科学基金; 中国国家自然科学基金;
关键词：
Blended polymer; Core-shell structured; Sandwich structured films; Energy storage performances; POLY(VINYLIDENE FLUORIDE) COMPOSITES; HIGH DIELECTRIC-CONSTANT; BREAKDOWN STRENGTH; NANOCOMPOSITES; NANOFIBERS; PERFORMANCE; CAPABILITY; INTERFACES; PARTICLES; FILLERS;
D O I：
10.1016/j.compositesb.2019.107429
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
In this study, the ferroelectric polyvinylidene fluoride (PVDF) blended with linear dielectric polymethyl methacrylate (PMMA) is chosen as polymer matrix (named as PMMA/PVDF). The effect of PMMA content and differently structured fillers on the microstructures and electrical properties of PMMA/PVDF-based composites have been investigated. The inorganic 0.5Ba(Zr0.2Ti0.8)O-3- 0.5(Ba0.7Ca0.3)TiO3 fibers (abbreviated as BCZT), BCZT embedded with Ag particles (BCZT+Ag), and core-shell structured BCZT+Ag@Al2O3 fibers as fillers were designed and prepared by electrospinning technology. As the insulating Al2O3 shell layer could relieve the dielectric difference between the BCZT and polymer matrix and confine the mobility of carriers provided by Ag, the energy storage density and efficiency are 4.02 J/cm(3) and 78.0% for the 3 vol% BCZT+Ag@Al2O3/40% PMMA/PVDF composites at an electric field of 320 kV/mm. To further improve the energy storage properties of the single-layered composites, the sandwich-structured composite films have been designed to improve the breakdown strength. The results show that the energy storage density and efficiency of sandwich-structured composite film with 40 wt% PMMA/PVDF as outer layer and 3 vol% BCZT+Ag@Al2O3/40% PMMA/PVDF as inter layer are 9.6 J/cm(3) and 69.8%, respectively, at an electric field of 400 kV/mm. This work presents an effective way to improve the energy storage properties of inorganic/polymer composites.
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页数：10
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