Twist Ferrocene Wires from Self-Assembly of Chiral Rod-Coil Organometallics

被引：5
|
作者：
Lin, Tz-Feng [1 ]
Ho, Rong-Ming [1 ]
Sung, Chien-Hung [2 ]
Ho, Ming-Shou [2 ]
Hsu, Chain-Shu [2 ]
机构：
[1] Natl Tsing Hua Univ, Dept Chem Engn, Hsinchu 30013, Taiwan
[2] Natl Chiao Tung Univ, Dept Appl Chem, Hsinchu 30010, Taiwan
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 25期
关键词：
amphiphiles; chirality; metallocenes; self-assembly; supramolecular chemistry; BLOCK-COPOLYMERS; PHOTONIC-CRYSTAL; MORPHOLOGIES; MONOLAYERS; MEMORY; PHASE; SENSE; FILMS; STEP;
D O I：
10.1002/chem.201000772
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) Let's twist again! A chiral rod-coil organometallic material, FC11, has been synthesized and shows liquidcrystalline behavior. By taking advantage of the self-assembly of the chiral Schiff based rod-coil molecule that is end-capped with ferrocene, the selfassembled superstructure can serve as a template to form iron-rich spiral superstructures (see graphic). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：7385 / 7388
页数：4
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