Twist Ferrocene Wires from Self-Assembly of Chiral Rod-Coil Organometallics

被引：5

作者：

Lin, Tz-Feng ^{[1
]}

Ho, Rong-Ming ^{[1
]}

Sung, Chien-Hung ^{[2
]}

Ho, Ming-Shou ^{[2
]}

Hsu, Chain-Shu ^{[2
]}

机构：

[1] Natl Tsing Hua Univ, Dept Chem Engn, Hsinchu 30013, Taiwan

[2] Natl Chiao Tung Univ, Dept Appl Chem, Hsinchu 30010, Taiwan

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 25期

关键词：

amphiphiles; chirality; metallocenes; self-assembly; supramolecular chemistry; BLOCK-COPOLYMERS; PHOTONIC-CRYSTAL; MORPHOLOGIES; MONOLAYERS; MEMORY; PHASE; SENSE; FILMS; STEP;

D O I：

10.1002/chem.201000772

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Let's twist again! A chiral rod-coil organometallic material, FC11, has been synthesized and shows liquidcrystalline behavior. By taking advantage of the self-assembly of the chiral Schiff based rod-coil molecule that is end-capped with ferrocene, the selfassembled superstructure can serve as a template to form iron-rich spiral superstructures (see graphic). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7385 / 7388

页数：4

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